Preparation, properties and crystal structures of nickel(II) complexes with acyclic schiff bases derived from 2,6-diformyl-4-chlorophenol and 1,5-diamino-3-thiapentane or 3,3?-diamino-N-methyl-dipropylamine (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Preparation, properties and crystal structures of nickel(II) complexes with acyclic schiff bases derived from 2,6-diformyl-4-chlorophenol and 1,5-diamino-3-thiapentane or 3,3?-diamino-N-methyl-dipropylamine (Articolo in rivista) (literal)

Anno

• 1986-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/S0020-1693(00)81334-1 (literal)

Alternative label

• U. Casellato, P. Guerriero, S. Tamburini, P.A. Vigato, R. Graziani (1986)
  Preparation, properties and crystal structures of nickel(II) complexes with acyclic schiff bases derived from 2,6-diformyl-4-chlorophenol and 1,5-diamino-3-thiapentane or 3,3?-diamino-N-methyl-dipropylamine
  in Inorganica Chimica Acta (Testo stamp.); Elsevier Sequoia, Lausanne (Svizzera)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• U. Casellato, P. Guerriero, S. Tamburini, P.A. Vigato, R. Graziani (literal)

Pagina inizio

• 75 (literal)

Pagina fine

• 82 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0020169300813341 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 119 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1 (literal)

Note

• Scopus (literal)
• ISI Web of Science (WOS) (literal)
• Science direct - Elsevier (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica e Tecnologia dei Radioelementi, C.N.R., Corso Stati Uniti 4, 35100 Padua, Italy Dipartimento di Chimica Inorganica, Metallorganica e Analittica, Via Loredan 4, 35100 Padua, Italy (literal)

Titolo

• Preparation, properties and crystal structures of nickel(II) complexes with acyclic schiff bases derived from 2,6-diformyl-4-chlorophenol and 1,5-diamino-3-thiapentane or 3,3?-diamino-N-methyl-dipropylamine (literal)

Abstract

• Nickel(II) complexes with the compartmental Schiff bases derived from 2,6-diformyl-4-chlorophenol and 1,5-diamino-3-thiapentane (H2L1) or 3,3?-diamino-N-methyl-dipropylamine (H2L2) were synthesized, and the crystal structures of [Ni(L1)- (py)2] and [Ni(L2)(dmf)]·H20 were determined by X-ray crystallography. Ni(L1)(py)2 is monoclinic, space group C2/c, with a= 18.457(6), b = 11.116(7), c= 16.098(6) Å, and ? = 115.79(5)°; Dc = 1.49 g cm-3 for Z = 4. The structure was refined to the final R of 6.9%. The molecule has C2 symmetry. The nickel atom is six-coordinated octahedral. Selected bond lengths are: NiO 2.04(1) Å, NiN (L1) 2.08(1) Å, NiN(py) 2.17(1) Å. [Ni(L2)(dmf)]·H2O is monoclinic, space group P21/n, with a = 17.329(6), b = 13.322(7), c = 12.476(7) Å and ? = 95.43(5)°; Dc = 1.45 g cm-3 for Z = 4. The structure was refined to the final R of 5.1%. The nickel atom is bonded in the octahedral geometry to the bianionic pentadentate ligand L2 and to one molecule of dimethylformamide. Selected bond lengths are: NiO (charged) 2.063(3) Å (mean value), NiO (neutral) 2.120(3) Å, NiN (planar) 2.050(3) Å (mean value), NiN (tetrahedral) 2.177(3) Å. (literal)

Editore

• Elsevier Sequoia (Editore)

Prodotto di

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR

• PAOLO GUERRIERO (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di chimica inorganica e delle superfici (ICIS) (Istituto)

Autore CNR di

• PAOLO GUERRIERO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Editore di

• Elsevier Sequoia (Editore)