Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers (Articolo in rivista)

Type
Label
  • Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Carotenuto, G.; Nicolais, L.; Perlo, P. (2006)
    Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers
    in Polymer engineering and science
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Carotenuto, G.; Nicolais, L.; Perlo, P. (literal)
Pagina inizio
  • 1016 (literal)
Pagina fine
  • 1020 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 46(8) (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • IMCB - CNR, Napoli CRF Torino (literal)
Titolo
  • Synthesis of polymer-embedded noble metal clusters by thermolysis of mercaptides dissolved in polymers (literal)
Abstract
  • Homoleptic mercaptides of noble metals (i.e., Me(SR)x, where R is a linear alkyl group, i.e., CnH2n+1) dissolved in polymer undergo a thermal degradation process at moderately low temperatures (180-250°C), producing metal atoms that then give nanosized metal particles by clustering. As an example, the preparation of palladium, gold, and silver clusters dispersed in polystyrene has been described, but such chemical route is a very general approach and a variety of metal/polymer combinations can be equivalently obtained. (literal)
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